{N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}bis(thiocyanato-κN)copper(II)
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چکیده
The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol-ecules. In each mol-ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N"-tridentate Schiff base and one N-bound thio-cyanate ligand. The second N-donor thio-cyanate group, located at the apical site, completes the coordination environment. In the crystal, inter-molecular C-H⋯S and C-H⋯N hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. Intra-molecular C-H⋯N inter-actions are also observed.
منابع مشابه
{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
The mol-ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio-cyanate ligands, forming a distorted octa-hedral geometry.
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In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio-cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯Br hydrogen bonds into chains propagating along [101].
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In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio-cyanate groups and one water mol-ecule. In the crystal, O-H⋯S hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-...
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In the title compound, [Cd(NCS)(2)(C(11)H(17)N(3))](n), the Cd(II) atom is octa-hedrally coordinated by the N,N',N''-tridentate Schiff base ligand and one terminal thio-cyanate N atom. Two trans-N:S-bridging thio-cyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(II) ions are linked by the thio-cyanate N:S-bridges into polymeric chains along the c axis.
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In the title compound, [CuCl(2)(C(11)H(17)N(3))], the Cu(II) ion is five-coordinated with a distorted square-pyramidal configuration. The three N atoms of the Schiff base ligand and one Cl atom are located in the basal plane, whereas the other Cl atom is apically positioned.
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